RHEA:13344          (APPROVED)

2 (S)-S-adenosyl-L-methionine + a menaquinone + reduced [flavodoxin] <=> 5'-deoxyadenosine + an 8-methylmenaquinone + 3 H(+) + L-methionine + oxidized [flavodoxin] + S-adenosyl-L-homocysteine

Last modified: 2018-09-06. Chemically balanced: yes.

2
(S)-S-adenosyl-L-methionine
CHEBI:142094
chebi link
Formula: C15H23N6O5S
Charge: 1
(no structure available)
+
a menaquinone
POLYMER:9537
(RHEA-COMP:9537)
Formula: C11H8O2(C5H8)n
Charge: (0)(0)n
ChEBI polymer: CHEBI:16374
chebi link
(no structure available)
+
reduced [flavodoxin]
GENERIC:10622
(RHEA-COMP:10622)
(no structure available)
FMNH2
CHEBI:57618
chebi link
Formula: C17H21N4O9P
Charge: -2
Position: 
<=>
5'-deoxyadenosine
CHEBI:17319
chebi link
Formula: C10H13N5O3
Charge: 0
(no structure available)
+
an 8-methylmenaquinone
POLYMER:14968
(RHEA-COMP:14968)
Formula: C12H10O2(C5H8)n
Charge: (0)(0)n
ChEBI polymer: CHEBI:142110
chebi link
(no structure available)
+
3
H+
CHEBI:15378
chebi link
Formula: H
Charge: 1
(no structure available)
+
L-methionine
CHEBI:57844
chebi link
Formula: C5H11NO2S
Charge: 0
(no structure available)
+
oxidized [flavodoxin]
GENERIC:10623
(RHEA-COMP:10623)
(no structure available)
FMN
CHEBI:58210
chebi link
Formula: C17H18N4O9P
Charge: -3
Position: 
+
S-adenosyl-L-homocysteine
CHEBI:57856
chebi link
Formula: C14H20N6O5S
Charge: 0
(no structure available)

Same participants, different directions

RHEA:13341 2 (S)-S-adenosyl-L-methionine + a menaquinone + reduced [flavodoxin] = 5'-deoxyadenosine + an 8-methylmenaquinone + 3 H(+) + L-methionine + oxidized [flavodoxin] + S-adenosyl-L-homocysteine
RHEA:13342 2 (S)-S-adenosyl-L-methionine + a menaquinone + reduced [flavodoxin] => 5'-deoxyadenosine + an 8-methylmenaquinone + 3 H(+) + L-methionine + oxidized [flavodoxin] + S-adenosyl-L-homocysteine
RHEA:13343 5'-deoxyadenosine + an 8-methylmenaquinone + 3 H(+) + L-methionine + oxidized [flavodoxin] + S-adenosyl-L-homocysteine => 2 (S)-S-adenosyl-L-methionine + a menaquinone + reduced [flavodoxin]

Links to other resources

Enzymes
UniProtKB
 [reviewed protein(s)]  [all proteins(s)]
Reactions
MetaCyc
RXN-18515

Reaction relationships

Outgoing
no data
Incoming
no data

Citations

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