RHEA:21094          (APPROVED)

dihydromacarpine + H(+) + S-adenosyl-L-homocysteine => 12-hydroxydihydrochelirubine + S-adenosyl-L-methionine

Last modified: 2018-12-21. Chemically balanced: yes.

12-hydroxydihydrochelirubine
CHEBI:15716
chebi link
Formula: C21H17NO6
Charge: 0
(no structure available)
+
S-adenosyl-L-methionine
CHEBI:59789
chebi link
Formula: C15H23N6O5S
Charge: 1
(no structure available)
<=
dihydromacarpine
CHEBI:18029
chebi link
Formula: C22H19NO6
Charge: 0
(no structure available)
+
H+
CHEBI:15378
chebi link
Formula: H
Charge: 1
(no structure available)
+
S-adenosyl-L-homocysteine
CHEBI:57856
chebi link
Formula: C14H20N6O5S
Charge: 0
(no structure available)

Same participants, different directions

RHEA:21092 12-hydroxydihydrochelirubine + S-adenosyl-L-methionine = dihydromacarpine + H(+) + S-adenosyl-L-homocysteine
RHEA:21093 12-hydroxydihydrochelirubine + S-adenosyl-L-methionine => dihydromacarpine + H(+) + S-adenosyl-L-homocysteine
RHEA:21095 12-hydroxydihydrochelirubine + S-adenosyl-L-methionine <=> dihydromacarpine + H(+) + S-adenosyl-L-homocysteine

Comments

Published in:
Kammerer, L., De-Eknamkul, W. and Zenk, M.H. Enzymic 12-hydroxylation and 12-O-methylation of dihydrochelirubine in dihydromacarpine formation by Thalictrum bulgaricum. Phytochemistry 36 (1994) 1409–1416.

Links to other resources

Enzymes
Enzyme classification
EC 2.1.1.120  [ENZYME]  [IntEnz]
UniProtKB
 [reviewed protein(s)]  [all proteins(s)]
Reactions
KEGG reaction
R04705
MetaCyc
2.1.1.120-RXN

Reaction relationships

Outgoing
no data
Incoming
no data

Citations

Loading...