RHEA:37058          (APPROVED)

3-(4-hydroxyphenyl)pyruvate + dimethylallyl diphosphate <=> 3-dimethylallyl-4-hydroxyphenylpyruvate + diphosphate

Last modified: 2017-03-20. Chemically balanced: yes.

3-(4-hydroxyphenyl)pyruvate
CHEBI:36242
chebi link
Formula: C9H7O4
Charge: -1
(no structure available)
+
dimethylallyl diphosphate
CHEBI:57623
chebi link
Formula: C5H9O7P2
Charge: -3
(no structure available)
<=>
3-dimethylallyl-4-hydroxyphenylpyruvate
CHEBI:74408
chebi link
Formula: C14H15O4
Charge: -1
(no structure available)
+
diphosphate
CHEBI:33019
chebi link
Formula: HO7P2
Charge: -3
(no structure available)

Same participants, different directions

RHEA:37055 3-(4-hydroxyphenyl)pyruvate + dimethylallyl diphosphate = 3-dimethylallyl-4-hydroxyphenylpyruvate + diphosphate
RHEA:37056 3-(4-hydroxyphenyl)pyruvate + dimethylallyl diphosphate => 3-dimethylallyl-4-hydroxyphenylpyruvate + diphosphate
RHEA:37057 3-dimethylallyl-4-hydroxyphenylpyruvate + diphosphate => 3-(4-hydroxyphenyl)pyruvate + dimethylallyl diphosphate

Comments

Published in:
"Novobiocin biosynthesis in Streptomyces spheroides: identification of a dimethylallyl diphosphate:4-hydroxyphenylpyruvate dimethylallyl transferase."
Steffensky M., Li S.-M., Vogler B., Heide L.
FEMS Microbiol. Ecol. 161:69-74(1998)

Links to other resources

Enzymes
Enzyme classification
EC 2.5.1.111  [ENZYME]  [IntEnz]
UniProtKB
 [reviewed protein(s)]  [all proteins(s)]
Reactions
KEGG reaction
R06757
MetaCyc
RXN-14631

Reaction relationships

Outgoing
no data
Incoming
no data

Citations

Loading...