RHEA:49634          (APPROVED)

(3R)-3-farnesyl-6-hydroxy-2,3,5-trimethyl-4-oxocyclohexa-1,5-diene-1-carboxylate + diphosphate + H(+) => (2E,6E)-farnesyl diphosphate + 3,5-dimethylorsellinate

Last modified: 2019-01-08Chemically balanced: yes.

Formula: C15H25O7P2
Charge: -3
(no structure available)
+
Formula: C10H11O4
Charge: -1
(no structure available)
<=
Formula: C25H34O4
Charge: -2
(no structure available)
+
Formula: HO7P2
Charge: -3
(no structure available)
+
Formula: H
Charge: 1
(no structure available)

Same participants, different directions

RHEA:49632 (2E,6E)-farnesyl diphosphate + 3,5-dimethylorsellinate = (3R)-3-farnesyl-6-hydroxy-2,3,5-trimethyl-4-oxocyclohexa-1,5-diene-1-carboxylate + diphosphate + H(+)
RHEA:49633 (2E,6E)-farnesyl diphosphate + 3,5-dimethylorsellinate => (3R)-3-farnesyl-6-hydroxy-2,3,5-trimethyl-4-oxocyclohexa-1,5-diene-1-carboxylate + diphosphate + H(+)
RHEA:49635 (2E,6E)-farnesyl diphosphate + 3,5-dimethylorsellinate <=> (3R)-3-farnesyl-6-hydroxy-2,3,5-trimethyl-4-oxocyclohexa-1,5-diene-1-carboxylate + diphosphate + H(+)

Comments

Published in: Itoh, T., Tokunaga, K., Radhakrishnan, E.K., Fujii, I., Abe, I. Ebizuka, Y. and Kushiro, T. Identification of a key prenyltransferase involved in biosynthesis of the most abundant fungal meroterpenoids derived from 3,5-dimethylorsellinic acid. ChemBioChem 13 (2012) 1132–1135.

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