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- Name help_outline (2E,6E,10E,14E)-geranylfarnesyl diphosphate Identifier CHEBI:57907 Charge -3 Formula C25H41O7P2 InChIKeyhelp_outline JMVSBFJBMXQNJW-GIXZANJISA-K SMILEShelp_outline CC(C)=CCC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\COP([O-])(=O)OP([O-])([O-])=O 2D coordinates Mol file for the small molecule Search links Involved in 23 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
- Name help_outline fusoxypene A Identifier CHEBI:191385 Charge 0 Formula C25H40 InChIKeyhelp_outline ZUDOUHDDSIJHEB-IGCMXNHPSA-N SMILEShelp_outline C1C2=C(C[C@]3([C@]1([C@@H](CC3)C(C)C)[H])C)[C@@H](CC[C@@]45[C@]2([C@]5(CC[C@H]4C)[H])C)C 2D coordinates Mol file for the small molecule Search links Involved in 1 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
- Name help_outline diphosphate Identifier CHEBI:33019 (Beilstein: 185088) help_outline Charge -3 Formula HO7P2 InChIKeyhelp_outline XPPKVPWEQAFLFU-UHFFFAOYSA-K SMILEShelp_outline OP([O-])(=O)OP([O-])([O-])=O 2D coordinates Mol file for the small molecule Search links Involved in 1,188 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
Cross-references
| RHEA:71979 | RHEA:71980 | RHEA:71981 | RHEA:71982 | |
|---|---|---|---|---|
| Reaction direction help_outline | undefined | left-to-right | right-to-left | bidirectional |
| UniProtKB help_outline |
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Publications
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Genome-based discovery of enantiomeric pentacyclic sesterterpenes catalyzed by fungal bifunctional terpene synthases.
Jiang L., Zhang X., Sato Y., Zhu G., Minami A., Zhang W., Ozaki T., Zhu B., Wang Z., Wang X., Lv K., Zhang J., Wang Y., Gao S., Liu C., Hsiang T., Zhang L., Oikawa H., Liu X.
Genome-based discovery of two previously unreported fungal bifunctional terpene synthases (BFTSs) from phytopathogenic fungi are reported: FoFS catalyzing the formation of fusoxypenes A-C (<b>1</b>-<b>3</b>) and (-)-astellatene (<b>4</b>) and AtAS capable of synthesizing preaspterpenacid I (<b>6</ ... >> More
Genome-based discovery of two previously unreported fungal bifunctional terpene synthases (BFTSs) from phytopathogenic fungi are reported: FoFS catalyzing the formation of fusoxypenes A-C (<b>1</b>-<b>3</b>) and (-)-astellatene (<b>4</b>) and AtAS capable of synthesizing preaspterpenacid I (<b>6</b>). Interestingly, FoFS and AtAS catalyzed the formation of enantiomeric sesterterpenes with a 5-6-7-3-5 ring system. C22-oxidative modification of preaspterpenacid I by AtP450 was characterized as well. Plausible cyclization pathways of the fusoxypenes were illustrated by DFT calculations. << Less
Org. Lett. 23:4645-4650(2021) [PubMed] [EuropePMC]
This publication is cited by 5 other entries.